Mike & Molly | 9:30pm on CBS

Season Premiere: After their engagement, trouble arises when Molly wants to start planning their wedding festivities, while Mike just wants to go fishing with the guys.

The Good Wife | 9pm on CBS

Season Premiere: While the staff at Lockhart/Gardner adjusts to new realities and relationships, Alicia must put aside distractions in her personal life to defend a Muslim student accused of murdering a Jewish classmate.

Castle | 10pm on ABC

Season 4 Premiere: Detective Beckett fights for her life as Castle, plagued by guilt over his role in the events, struggles to uncover who’s behind her brutal shooting; Back at the precinct, Ryan and Esposito have to adjust, as Victoria “Iron” Gates becomes their new uncompromising Captain.

The Secret Circle | 9pm on The CW

Series Premiere: After her mother dies in a mysterious accident, Cassie Blake moves to a small town to live with her grandmother; after a series of strange and dangerous events, Cassie’s new friends reveal a secret.

Melissa & Joey | 8pm on ABC Family

Season Finale: Mel has a difficult time discussing teenage pressures with Lennox; Joe finds himself coming into some money, so he quits his “manny” job.

The Big C | 10:30pm on Showtime

Lee and Dr. Sherman propel Cathy to a major crossroads; Adam tries to find his uncle who has gone missing.

Entourage | 10:30pm on HBO

Series Finale: Has Vince found “the one”?! Will E, Sloan and their spawn live happily ever after?! Do Ari and Dana Gordon end up together?!

Portraits from Ground Zero | 10pm on A&E

A photographer with unprecedented access to the rescue and recovery operations at Ground Zero tracks down the people in her best pictures and gets them to tell the riveting personal stories behind the photos.

Whisker Wars | 11pm on IFC

The team competes in the Motor City Beard and Mustache Championships in Detroit.

Louie | 10:30pm on FX

Season Finale: This last ep involves the airport and New Jersey, so you know Louie will be even more miserable than usual.

Sons of Anarchy | 10pm on FX

Season 4 Premiere: 14 months have passed and Jax, Clay and co. are being released from prison.

The Closer | 9pm on TNT

When a popular, young pop star’s overbearing stage father vanishes, Brenda follows the trail left behind.

Breaking Bad | 10pm on AMC

Skyler develops a solution for her money troubles; Hank enlists Walt to investigate a theory.

Rescue Me | 10pm on FX

Colleen and Black Shawn walk down the aisle and wed, but the day’s glow becomes an inferno when a major fire breaks out.

Tosh.0 | 10pm on Comedy Central

Daniel Tosh — the comedy world’s expert in all things hilarious online — entertains with a batch of new videos and clips, as well as irreverent commentary.